Cargando…

Merging Grubbs second-generation catalyst with photocatalysis enables Z-selective metathesis of olefins: scope, limitations, and mechanism

Olefin cross-metathesis is a cornerstone reaction in organic synthesis where stereoselectivity is typically governed by the structure of the catalyst. In this work, we show that merging Grubbs second generation catalyst, a classical E-selective catalyst, with a readily available photocatalyst, enabl...

Descripción completa

Detalles Bibliográficos
Autores principales: Chérif, Saïf Eddine, Ghosh, Avisek, Chelli, Saloua, Dixon, Isabelle M., Kraiem, Jamil, Lakhdar, Sami
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9600307/
https://www.ncbi.nlm.nih.gov/pubmed/36349104
http://dx.doi.org/10.1039/d2sc03961c