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From mixed group 13 cations [M(AlCp*)(3)](+) (M = Ga/In/Tl) to an Al(4)(+) cluster
AlCp*-complexes with transition metals have shown to be highly reactive and enable C–H or Si–H bond activation. Yet, complexes of AlCp* with low-valent main-group metals are scarce. Here, we report the syntheses of [M(AlCp*)(3)][Al(OR(F))(4)] (R(F) = C(CF(3))(3)) with M = Ga, In, Tl, which include t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9600313/ https://www.ncbi.nlm.nih.gov/pubmed/36349105 http://dx.doi.org/10.1039/d2sc04637g |