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Synthesis of Trifluoromethylated Monoterpene Amino Alcohols

For the first time, monoterpene trifluoromethylated β-hydroxy-benzyl-O-oximes were synthesized in 81–95% yields by nucleophilic addition of the Ruppert–Prakash reagent (TMSCF(3)) to the corresponding β-keto-benzyl-O-oximes based on (+)-nopinone, (−)-verbanone and (+)-camphoroquinone. Trifluoromethyl...

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Detalles Bibliográficos
Autores principales: Petrova, Polina A., Sudarikov, Denis V., Frolova, Larisa L., Rumyantcev, Roman V., Rubtsova, Svetlana A., Kutchin, Aleksandr V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9607099/
https://www.ncbi.nlm.nih.gov/pubmed/36296661
http://dx.doi.org/10.3390/molecules27207068