A New Sustainable Multistep Catalytic Process from Benzene to Caprolactam: Amination, Hydroximation and Beckmann Rearrangement Promoted and Catalyzed by Trifluoroacetic Acid

Here we report some results on a 3 steps benzene caprolactam process via amination, aniline Hydroxymation and Beckmann rearrangement. The amination proceeds with hydroxylamine trifluoroacetate, with 97% of conversion and selectivity of 90%, catalyzed by V compounds. We achieve 98% of conversion and...

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Detalles Bibliográficos
Autores principales: Cazzador, G., Manzato, L., Ronchin, L., Sadraoui, C., Vavasori, A., Zanella, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9607771/
https://www.ncbi.nlm.nih.gov/pubmed/36320430
http://dx.doi.org/10.1007/s10562-022-04207-9

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9607771/
https://www.ncbi.nlm.nih.gov/pubmed/36320430
http://dx.doi.org/10.1007/s10562-022-04207-9

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