Triflamidation of Allyl-Containing Substances:Unusual Dehydrobromination vs. Intramolecular Heterocyclization

Allyl halides with triflamide under oxidative conditions form halogen-substituted amidines. Allyl cyanide reacts with triflamide in acetonitrile or THF solutions in the presence of NBS to give the products of bromotriflamidation with a solvent interception, whereas in CH(2)Cl(2) two regioisomers of...

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Detalles Bibliográficos
Autores principales: Ganin, Anton S., Moskalik, Mikhail Yu., Garagan, Ivan A., Astakhova, Vera V., Shainyan, Bagrat A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9610413/
https://www.ncbi.nlm.nih.gov/pubmed/36296503
http://dx.doi.org/10.3390/molecules27206910

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9610413/
https://www.ncbi.nlm.nih.gov/pubmed/36296503
http://dx.doi.org/10.3390/molecules27206910

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