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Photocatalytic deracemisation of cobalt(iii) complexes with fourfold stereogenicity
The deracemisation of fourfold stereogenic cobalt(iii) diketonates with a chiral photocatalyst is described. With only 0.5 mol% menthyl Ru(bpy)(3)(2+) photocatalyst, an enantiomeric enrichment of up to 88 : 12 e.r. was obtained for the major meridional diastereomers. Moreover, a distribution of conf...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9623447/ https://www.ncbi.nlm.nih.gov/pubmed/36254723 http://dx.doi.org/10.1039/d2cc05196f |