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Enhancing magnetic coupling through protonation of benzylideneaniline-bridged diradicals and comparison with stilbene- and azobenzene-based diradicals

Taking nitroxide radicals as spin sources, we explore the intramolecular magnetic coupling interactions of the trans- and cis-forms of benzylideneaniline (BA)-bridged diradicals, in which the central –CH[double bond, length as m-dash]N– unit can undergo single protonation to convert to its protonate...

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Detalles Bibliográficos
Autores principales: Zhang, Fengying, Feng, Yiwei, Song, Xinyu, Bu, Yuxiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9627958/
https://www.ncbi.nlm.nih.gov/pubmed/36349011
http://dx.doi.org/10.1039/d2ra05115j