Spin-state crossover in photo-catalyzed nitrile dihydroboration via Mn-thiolate cooperation

The role of S-donors in ligand-assisted catalysis using first-row metals has not been broadly investigated. Herein is described a combined experimental and computational mechanistic study of the dihydroboration of nitriles with pinacolborane (HBpin) catalyzed by the Mn(i) complex, Mn(κ(3)-S(Me)NS)(C...

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Detalles Bibliográficos
Autores principales: Elsby, Matthew R., Oh, Changjin, Son, Mina, Kim, Scott Y. H., Baik, Mu-Hyun, Baker, R. Tom
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629026/
https://www.ncbi.nlm.nih.gov/pubmed/36382284
http://dx.doi.org/10.1039/d2sc04339d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629026/
https://www.ncbi.nlm.nih.gov/pubmed/36382284
http://dx.doi.org/10.1039/d2sc04339d

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