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Spin-state crossover in photo-catalyzed nitrile dihydroboration via Mn-thiolate cooperation
The role of S-donors in ligand-assisted catalysis using first-row metals has not been broadly investigated. Herein is described a combined experimental and computational mechanistic study of the dihydroboration of nitriles with pinacolborane (HBpin) catalyzed by the Mn(i) complex, Mn(κ(3)-S(Me)NS)(C...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629026/ https://www.ncbi.nlm.nih.gov/pubmed/36382284 http://dx.doi.org/10.1039/d2sc04339d |