Hydroxy-directed iridium-catalyzed enantioselective formal β-C(sp(2))–H allylic alkylation of α,β-unsaturated carbonyls

Hydroxy-directed iridium-catalyzed enantioselective formal β-C(sp(2))–H allylic alkylation of kojic acid and structurally related α,β-unsaturated carbonyl compounds is developed. This reaction, catalyzed by an Ir(i)/(P,olefin) complex, utilizes the nucleophilic character of α-hydroxy α,β-unsaturated...

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Detalles Bibliográficos
Autores principales: Mitra, Sankash, Sarkar, Rahul, Chakrabarty, Aditya, Mukherjee, Santanu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629034/
https://www.ncbi.nlm.nih.gov/pubmed/36382287
http://dx.doi.org/10.1039/d2sc03966d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629034/
https://www.ncbi.nlm.nih.gov/pubmed/36382287
http://dx.doi.org/10.1039/d2sc03966d

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