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A bis-NHC–CAAC dimer derived dicationic diradical

The isolation of carbon-centered diradicals is always challenging due to synthetic difficulties and their limited stability. Herein we report the synthesis of a trans-1,4-cyclohexylene bridged bis-NHC–CAAC dimer derived thermally stable dicationic diradical. The diradical character of this compound...

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Detalles Bibliográficos
Autores principales: Nayak, Mithilesh Kumar, Sarkar, Pallavi, Elvers, Benedict J., Mehta, Sakshi, Zhang, Fangyuan, Chrysochos, Nicolas, Krummenacher, Ivo, Vijayakanth, Thangavel, Narayanan, Ramakirushnan Suriya, Dolai, Ramapada, Roy, Biswarup, Malik, Vishal, Rawat, Hemant, Mondal, Abhishake, Boomishankar, Ramamoorthy, Pati, Swapan K., Braunschweig, Holger, Schulzke, Carola, Ravat, Prince, Jana, Anukul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629079/
https://www.ncbi.nlm.nih.gov/pubmed/36382295
http://dx.doi.org/10.1039/d2sc03937k