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One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
Chlorocarboxylation of toluene was achieved by photoirradiation of a chlorine dioxide radical (ClO(2)˙) under ambient conditions (298 K and 1 atm). 2- and 4-Chlorobenzoic acids were obtained in a 1 : 1 yield ratio. This is a single step synthesis under metal-free and mild conditions.
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629127/ https://www.ncbi.nlm.nih.gov/pubmed/36382151 http://dx.doi.org/10.1039/d2ra06591f |