One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation

Chlorocarboxylation of toluene was achieved by photoirradiation of a chlorine dioxide radical (ClO(2)˙) under ambient conditions (298 K and 1 atm). 2- and 4-Chlorobenzoic acids were obtained in a 1 : 1 yield ratio. This is a single step synthesis under metal-free and mild conditions.

Detalles Bibliográficos
Autores principales: Ohno, Shohei, Asahara, Haruyasu, Inoue, Tsuyoshi, Ohkubo, Kei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629127/
https://www.ncbi.nlm.nih.gov/pubmed/36382151
http://dx.doi.org/10.1039/d2ra06591f
Descripción
Sumario:Chlorocarboxylation of toluene was achieved by photoirradiation of a chlorine dioxide radical (ClO(2)˙) under ambient conditions (298 K and 1 atm). 2- and 4-Chlorobenzoic acids were obtained in a 1 : 1 yield ratio. This is a single step synthesis under metal-free and mild conditions.

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