One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation

Chlorocarboxylation of toluene was achieved by photoirradiation of a chlorine dioxide radical (ClO(2)˙) under ambient conditions (298 K and 1 atm). 2- and 4-Chlorobenzoic acids were obtained in a 1 : 1 yield ratio. This is a single step synthesis under metal-free and mild conditions.

Detalles Bibliográficos
Autores principales: Ohno, Shohei, Asahara, Haruyasu, Inoue, Tsuyoshi, Ohkubo, Kei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629127/
https://www.ncbi.nlm.nih.gov/pubmed/36382151
http://dx.doi.org/10.1039/d2ra06591f
_version_ 1784823336308572160
author Ohno, Shohei
Asahara, Haruyasu
Inoue, Tsuyoshi
Ohkubo, Kei
author_facet Ohno, Shohei
Asahara, Haruyasu
Inoue, Tsuyoshi
Ohkubo, Kei
author_sort Ohno, Shohei
collection PubMed
description Chlorocarboxylation of toluene was achieved by photoirradiation of a chlorine dioxide radical (ClO(2)˙) under ambient conditions (298 K and 1 atm). 2- and 4-Chlorobenzoic acids were obtained in a 1 : 1 yield ratio. This is a single step synthesis under metal-free and mild conditions.
format Online
Article
Text
id pubmed-9629127
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-96291272022-11-14 One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation Ohno, Shohei Asahara, Haruyasu Inoue, Tsuyoshi Ohkubo, Kei RSC Adv Chemistry Chlorocarboxylation of toluene was achieved by photoirradiation of a chlorine dioxide radical (ClO(2)˙) under ambient conditions (298 K and 1 atm). 2- and 4-Chlorobenzoic acids were obtained in a 1 : 1 yield ratio. This is a single step synthesis under metal-free and mild conditions. The Royal Society of Chemistry 2022-11-02 /pmc/articles/PMC9629127/ /pubmed/36382151 http://dx.doi.org/10.1039/d2ra06591f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Ohno, Shohei
Asahara, Haruyasu
Inoue, Tsuyoshi
Ohkubo, Kei
One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
title One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
title_full One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
title_fullStr One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
title_full_unstemmed One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
title_short One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
title_sort one-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9629127/
https://www.ncbi.nlm.nih.gov/pubmed/36382151
http://dx.doi.org/10.1039/d2ra06591f
work_keys_str_mv AT ohnoshohei onepotchlorocarboxylationoftolueneswithchlorinedioxideunderphotoirradiation
AT asaharaharuyasu onepotchlorocarboxylationoftolueneswithchlorinedioxideunderphotoirradiation
AT inouetsuyoshi onepotchlorocarboxylationoftolueneswithchlorinedioxideunderphotoirradiation
AT ohkubokei onepotchlorocarboxylationoftolueneswithchlorinedioxideunderphotoirradiation

Ejemplares similares