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Stereoselective Transesterification of P‐Chirogenic Hydroxybinaphthyl Phosphinates

The substitution reaction of phosphinates with a binaphthyloxy group at the phosphorus atom with lithium alkoxides proceeded with good to high efficiencies to give P‐chirogenic phosphinates with a high enantiomeric ratio. As alcohols, primary, secondary, and tertiary alcohols could be used, and the...

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Detalles Bibliográficos
Autores principales: Kawajiri, Akari, Udagawa, Taro, Minoura, Mao, Murai, Toshiaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9630046/
https://www.ncbi.nlm.nih.gov/pubmed/35261188
http://dx.doi.org/10.1002/open.202100294