Push and Pull Effect of Methoxy and Nitro Groups Modifies the Spin-State Switching Temperature in Fe(III) Complexes

[Image: see text] We have explored the impact of electron-donating (methoxy) and electron-withdrawing (nitro) substituents on SalEen ligand based spin crossover (SCO) behavior of Fe(III) complexes. Thus, 3-X-substituted SalEen ligands were employed to prepare [Fe(3-X-SalEen)(2)]·NCSe, where X = OMe...

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Detalles Bibliográficos
Autores principales: Dey, Bijoy, Mehta, Sakshi, Mondal, Abhishake, Cirera, Jordi, Colacio, Enrique, Chandrasekhar, Vadapalli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9631739/
https://www.ncbi.nlm.nih.gov/pubmed/36340084
http://dx.doi.org/10.1021/acsomega.2c05380

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9631739/
https://www.ncbi.nlm.nih.gov/pubmed/36340084
http://dx.doi.org/10.1021/acsomega.2c05380

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