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Construction of a High Nuclear Gadolinium Cluster with Enhanced Magnetocaloric Effect through Structural Transition
[Image: see text] Starting from a dinuclear complex {Gd(2)(L)(2)(NO(3))(4)(H(2)O)(2)}·2(CH(3)CN) (1) based on 2,6-dimethoxyphenol (HL), a nonanuclear cluster {Gd(9)(L)(4)(μ(4)-OH)(2)(μ(3)-OH)(8)(μ(2)-OCH(3))(4)(NO(3))(8) (H(2)O)(8)}(OH)·2H(2)O (2) was obtained via modulating the amount of the ligand...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9631744/ https://www.ncbi.nlm.nih.gov/pubmed/36340128 http://dx.doi.org/10.1021/acsomega.2c04412 |