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Studies of the Temperature Dependence of the Structure and Magnetism of a Hexagonal-Bipyramidal Dysprosium(III) Single-Molecule Magnet

[Image: see text] The hexagonal-bipyramidal lanthanide(III) complex [Dy(O(t)Bu)Cl(18-C-6)][BPh(4)] (1; 18-C-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane ether) displays an energy barrier for magnetization reversal (U(eff)) of ca. 1000 K in a zero direct-current field. Temperature-dependent X-ray diffra...

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Detalles Bibliográficos
Autores principales: Ding, You-Song, Blackmore, William J. A., Zhai, Yuan-Qi, Giansiracusa, Marcus J., Reta, Daniel, Vitorica-Yrezabal, Inigo, Winpenny, Richard E. P., Chilton, Nicholas F., Zheng, Yan-Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9632936/
https://www.ncbi.nlm.nih.gov/pubmed/34939782
http://dx.doi.org/10.1021/acs.inorgchem.1c02779