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Synthesis of I((III))/S((VI)) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds

The development of novel methodologies for the introduction of the sulfoxonium group under mild conditions is appealing but remains underexplored. Herein we report the synthesis of a class of hypervalent iodine reagents with a transferrable sulfoxonium group. These compounds enable mixed iodonium-su...

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Detalles Bibliográficos
Autores principales: Li, Li, Deng, Kun, Xing, Yajie, Ma, Cheng, Ni, Shao-Fei, Wang, Zhaofeng, Huang, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9633813/
https://www.ncbi.nlm.nih.gov/pubmed/36329065
http://dx.doi.org/10.1038/s41467-022-34401-7