Crystallographic Detection of the Spin State in Fe(III) Complexes

[Image: see text] We report a single example of thermal spin crossover in a series of Fe(III) complexes, [Fe(III)(R-sal(2)323)](+), which typically stabilize the low-spin (S = 1/2) state. Single-crystal X-ray diffraction analysis of 53 such complexes with varying “R” groups, charge-balancing anions,...

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Detalles Bibliográficos
Autores principales: Kelly, Conor T., Griffin, Michael, Esien, Kane, Felton, Solveig, Müller-Bunz, Helge, Morgan, Grace G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9634697/
https://www.ncbi.nlm.nih.gov/pubmed/36345384
http://dx.doi.org/10.1021/acs.cgd.2c00468

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9634697/
https://www.ncbi.nlm.nih.gov/pubmed/36345384
http://dx.doi.org/10.1021/acs.cgd.2c00468

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