Migratory Insertion of CO into a Au–C Bond

[Image: see text] A MeDalPhos-ligated gold(III) metallafluorene complex, generated via C–C oxidative addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and computational studies show that this proceeds via a hitherto unknown migratory insertion of CO into a Au(III)–C bond....

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Detalles Bibliográficos
Autores principales: Cadge, Jamie A., Gates, Paul J., Bower, John F., Russell, Christopher A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9634805/
https://www.ncbi.nlm.nih.gov/pubmed/36282061
http://dx.doi.org/10.1021/jacs.2c10432

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9634805/
https://www.ncbi.nlm.nih.gov/pubmed/36282061
http://dx.doi.org/10.1021/jacs.2c10432

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