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Isolation and crystal and molecular structures of [(C(5)H(2)Br(3))(2)Fe], [(C(5)HBr(4))(2)Fe] and [(C(5)Br(5))(C(5)Br(4)HgBr)Fe]
The reaction of [(C(5)H(3)Br(2))(2)Fe] with lithium tetramethylpiperidinide (LiTMP) in a 1:10 molar ratio in tetrahydrofuran yields, after quenching with C(2)H(2)Br(4), a mixture of the polybromoferrocenes [C(10)H(10–n )Br( n )Fe] with n = 4–9, from which single crystals of bis(1,2,3-tribromo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635591/ https://www.ncbi.nlm.nih.gov/pubmed/36331882 http://dx.doi.org/10.1107/S205322962200955X |