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Isolation and crystal and molecular structures of [(C(5)H(2)Br(3))(2)Fe], [(C(5)HBr(4))(2)Fe] and [(C(5)Br(5))(C(5)Br(4)HgBr)Fe]

The reaction of [(C(5)H(3)Br(2))(2)Fe] with lithium tetramethylpiperidinide (LiTMP) in a 1:10 molar ratio in tetrahydrofuran yields, after quenching with C(2)H(2)Br(4), a mixture of the polybromoferrocenes [C(10)H(10–n )Br( n )Fe] with n = 4–9, from which single crystals of bis(1,2,3-tribromo...

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Detalles Bibliográficos
Autores principales:	Blockhaus, Tobias, Sünkel, Karlheinz
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2022
Materias:	Halogen, Chalcogen, Pnictogen and Tetrel Bonds: Structural Chemistry and Beyond
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635591/ https://www.ncbi.nlm.nih.gov/pubmed/36331882 http://dx.doi.org/10.1107/S205322962200955X

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