Anion···Anion [AuI(4)](−)···[AuI(2)](−) Complex Trapped in the Solid State by Tetramethylammonium Cations

[Image: see text] A discrete π-hole···σ-hole dimer is synthesized and X-ray characterized. It presents a perfect thumbtack geometry where the σ-hole of the linear [AuI(2)](−) anion points to the π-hole located above the central Au-atom of the [AuI(4)](−) anion. Such discrete π-hole···σ-hole dimers a...

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Detalles Bibliográficos
Autores principales: Andreo, Luca, Gomila, Rosa M., Priola, Emanuele, Giordana, Alessia, Pantaleone, Stefano, Diana, Eliano, Mahmoudi, Ghodrat, Frontera, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635596/
https://www.ncbi.nlm.nih.gov/pubmed/36345385
http://dx.doi.org/10.1021/acs.cgd.2c00749

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635596/
https://www.ncbi.nlm.nih.gov/pubmed/36345385
http://dx.doi.org/10.1021/acs.cgd.2c00749

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