Cargando…
Anion···Anion [AuI(4)](−)···[AuI(2)](−) Complex Trapped in the Solid State by Tetramethylammonium Cations
[Image: see text] A discrete π-hole···σ-hole dimer is synthesized and X-ray characterized. It presents a perfect thumbtack geometry where the σ-hole of the linear [AuI(2)](−) anion points to the π-hole located above the central Au-atom of the [AuI(4)](−) anion. Such discrete π-hole···σ-hole dimers a...
| Autores principales: | , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9635596/ https://www.ncbi.nlm.nih.gov/pubmed/36345385 http://dx.doi.org/10.1021/acs.cgd.2c00749 |