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Sila-spirocyclization involving unstrained C(sp(3))−Si bond cleavage

C − Si Bond cleavage is one of the key elemental steps for a wide variety of silicon-based transformations. However, the cleavage of unstrained Si−C(sp(3)) bonds catalyzed by transition metal are still in their infancy. They generally involve the insertion of a M − C(sp(2)) species into the C − Si b...

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Detalles Bibliográficos
Autores principales: Shi, Yufeng, Shi, Xiaonan, Zhang, Jinyu, Qin, Ying, Li, Bo, Zhao, Dongbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9637223/
https://www.ncbi.nlm.nih.gov/pubmed/36335183
http://dx.doi.org/10.1038/s41467-022-34466-4