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On the Role of Noncovalent Ligand-Substrate Interactions in Au(I) Catalysis: An Experimental and Computational Study of Protodeauration

[Image: see text] A systematic study of protodeauration, a crucial step often found in gold catalysis, was performed using isolated vinyl gold(I) complexes. By varying substituents on gold complexes, we explore how their properties influence protodeauration. Phenols were employed as the proton sourc...

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Detalles Bibliográficos
Autores principales: Jo, Taegeun, Taschinski, Svenja, Leach, Isaac F., Bauer, Christina, Hashmi, A. Stephen K., Klein, Johannes E. M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638986/
https://www.ncbi.nlm.nih.gov/pubmed/36366761
http://dx.doi.org/10.1021/acscatal.2c03384