Serial Femtosecond Crystallography Reveals the Role of Water in the One- or Two-Electron Redox Chemistry of Compound I in the Catalytic Cycle of the B-Type Dye-Decolorizing Peroxidase DtpB

[Image: see text] Controlling the reactivity of high-valent Fe(IV)–O catalytic intermediates, Compounds I and II, generated in heme enzymes upon reaction with dioxygen or hydrogen peroxide, is important for function. It has been hypothesized that the presence (wet) or absence (dry) of distal heme po...

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Detalles Bibliográficos
Autores principales: Lučić, Marina, Wilson, Michael T., Tosha, Takehiko, Sugimoto, Hiroshi, Shilova, Anastasya, Axford, Danny, Owen, Robin L., Hough, Michael A., Worrall, Jonathan A. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638988/
https://www.ncbi.nlm.nih.gov/pubmed/36366763
http://dx.doi.org/10.1021/acscatal.2c03754

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638988/
https://www.ncbi.nlm.nih.gov/pubmed/36366763
http://dx.doi.org/10.1021/acscatal.2c03754

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