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Unusually Chemoselective Photocyclization of 2-(Hydroxyimino)aldehydes to Cyclobutanol Oximes: Synthetic, Stereochemical, and Mechanistic Aspects

[Image: see text] Photocyclization of carbonyl compounds (known as the Norrish–Yang reaction) to yield cyclobutanols is, in general, accompanied by fragmentation reactions. The latter are predominant in the case of aldehydes so that secondary cyclobutanols are not considered accessible via the strai...

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Detalles Bibliográficos
Autores principales: Di Sabato, Antonio, D’Acunzo, Francesca, Filippini, Dario, Vetica, Fabrizio, Brasiello, Antonio, Corinti, Davide, Bodo, Enrico, Michenzi, Cinzia, Panzetta, Edoardo, Gentili, Patrizia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9639046/
https://www.ncbi.nlm.nih.gov/pubmed/36198009
http://dx.doi.org/10.1021/acs.joc.2c01503