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Effects of fluorine bonding and nonbonding interactions on (19)F chemical shifts
(19)F-NMR signals are sensitive to local electrostatic fields and are useful in probing protein structures and dynamics. Here, we used chemically identical ortho-F nuclei in N-phenyl γ-lactams to investigate the relationship between (19)F NMR chemical shifts and local environments. By varying the st...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9644289/ https://www.ncbi.nlm.nih.gov/pubmed/36415555 http://dx.doi.org/10.1039/d2ra06660b |