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Heterotrimetallic Assemblies with 1,2,4,5-Tetrakis(diphenylphosphino)benzene Bridges: Constructs for Controlling the Separation and Spatial Orientation of Redox-Active Metallodithiolene Groups

[Image: see text] Metallodithiolene complexes of the type [(R(2)C(2)S(2))M(η(2)-tpbz)] [R = CN, Ph, or p-anisyl; M = Ni(2+), Pd(2+), or Pt(2+); tpbz = 1,2,4,5-tetrakis(diphenylphosphino)benzene] chelate transition metals ions to form trimetallic arrays [[(R(2)C(2)S(2))M(tpbz)](2)M′](n+), where M′ is...

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Detalles Bibliográficos
Autores principales: Kumar, Satyendra, Selvachandran, Malathy, Wu, Che, Pascal, Robert A., Zhang, Xiaodong, Grusenmeyer, Tod, Schmehl, Russell H., Sproules, Stephen, Mague, Joel T., Donahue, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9644372/
https://www.ncbi.nlm.nih.gov/pubmed/36282620
http://dx.doi.org/10.1021/acs.inorgchem.2c03112