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Heterotrimetallic Assemblies with 1,2,4,5-Tetrakis(diphenylphosphino)benzene Bridges: Constructs for Controlling the Separation and Spatial Orientation of Redox-Active Metallodithiolene Groups
[Image: see text] Metallodithiolene complexes of the type [(R(2)C(2)S(2))M(η(2)-tpbz)] [R = CN, Ph, or p-anisyl; M = Ni(2+), Pd(2+), or Pt(2+); tpbz = 1,2,4,5-tetrakis(diphenylphosphino)benzene] chelate transition metals ions to form trimetallic arrays [[(R(2)C(2)S(2))M(tpbz)](2)M′](n+), where M′ is...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9644372/ https://www.ncbi.nlm.nih.gov/pubmed/36282620 http://dx.doi.org/10.1021/acs.inorgchem.2c03112 |