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Facial vs. meridional coordination in gaseous Ni(ii)–hexacyclen complexes revealed with infrared ion spectroscopy
We report fingerprint infrared multiple-photon dissociation (IRMPD) spectra of the isolated gaseous hexa-coordinated complex of the macrocycle hexa-aza-18-crown-6 (hexacyclen, 1,4,7,10,13,16-hexaazacyclooctadecane, 18-azacrown-6) with Ni(2+). The metal–ligand complexes are generated using electrospr...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9644429/ https://www.ncbi.nlm.nih.gov/pubmed/36317665 http://dx.doi.org/10.1039/d2cp03871d |