Cooperative Intrinsic Basicity and Hydrogen Bonding Render SmI(2) More Azaphilic than Oxophilic

[Image: see text] It has been recently shown that SmI(2) is more azaphilic than oxophilic. Density functional theory calculations reveal that coordination of 1–3 molecules of ethylenediamine is more exothermic by up to 10 kcal/mol than coordination of the corresponding number of ethylene glycol mole...

Descripción completa

Detalles Bibliográficos
Autores principales: Kolin, Gil, Schwartz, Renana, Shuster, Daniel, Major, Dan Thomas, Hoz, Shmaryahu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9647864/
https://www.ncbi.nlm.nih.gov/pubmed/36385862
http://dx.doi.org/10.1021/acsomega.2c04680

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9647864/
https://www.ncbi.nlm.nih.gov/pubmed/36385862
http://dx.doi.org/10.1021/acsomega.2c04680

Ejemplares similares