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Cooperative Intrinsic Basicity and Hydrogen Bonding Render SmI(2) More Azaphilic than Oxophilic
[Image: see text] It has been recently shown that SmI(2) is more azaphilic than oxophilic. Density functional theory calculations reveal that coordination of 1–3 molecules of ethylenediamine is more exothermic by up to 10 kcal/mol than coordination of the corresponding number of ethylene glycol mole...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9647864/ https://www.ncbi.nlm.nih.gov/pubmed/36385862 http://dx.doi.org/10.1021/acsomega.2c04680 |