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Rotaxanes with dynamic mechanical chirality: Systematic studies on synthesis, enantiomer separation, racemization, and chiral-prochiral interconversion

Dynamic mechanical chirality of [2]rotaxane consisting of a C (s) symmetric wheel and a C (2v) symmetric axle is discussed via the synthesis, enantiomer separation, racemization, and chiral-prochiral interconversion. This [2]rotaxane is achiral and/or prochiral when its wheel locates at the center o...

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Detalles Bibliográficos
Autores principales: Ishiwari, Fumitaka, Takata, Toshikazu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9650364/
https://www.ncbi.nlm.nih.gov/pubmed/36386001
http://dx.doi.org/10.3389/fchem.2022.1025977