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Rotaxanes with dynamic mechanical chirality: Systematic studies on synthesis, enantiomer separation, racemization, and chiral-prochiral interconversion
Dynamic mechanical chirality of [2]rotaxane consisting of a C (s) symmetric wheel and a C (2v) symmetric axle is discussed via the synthesis, enantiomer separation, racemization, and chiral-prochiral interconversion. This [2]rotaxane is achiral and/or prochiral when its wheel locates at the center o...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9650364/ https://www.ncbi.nlm.nih.gov/pubmed/36386001 http://dx.doi.org/10.3389/fchem.2022.1025977 |