The Influence of the Electron Density in Acyl Protecting Groups on the Selectivity of Galactose Formation

[Image: see text] The stereoselective formation of 1,2-cis-glycosidic bonds is a major bottleneck in the synthesis of carbohydrates. We here investigate how the electron density in acyl protecting groups influences the stereoselectivity by fine-tuning the efficiency of remote participation. Electron...

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Detalles Bibliográficos
Autores principales: Greis, Kim, Leichnitz, Sabrina, Kirschbaum, Carla, Chang, Chun-Wei, Lin, Mei-Huei, Meijer, Gerard, von Helden, Gert, Seeberger, Peter H., Pagel, Kevin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9650713/
https://www.ncbi.nlm.nih.gov/pubmed/36289569
http://dx.doi.org/10.1021/jacs.2c05859

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9650713/
https://www.ncbi.nlm.nih.gov/pubmed/36289569
http://dx.doi.org/10.1021/jacs.2c05859

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