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The Influence of the Electron Density in Acyl Protecting Groups on the Selectivity of Galactose Formation
[Image: see text] The stereoselective formation of 1,2-cis-glycosidic bonds is a major bottleneck in the synthesis of carbohydrates. We here investigate how the electron density in acyl protecting groups influences the stereoselectivity by fine-tuning the efficiency of remote participation. Electron...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9650713/ https://www.ncbi.nlm.nih.gov/pubmed/36289569 http://dx.doi.org/10.1021/jacs.2c05859 |