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Synthesis of Sterically Shielded Nitroxides Using the Reaction of Nitrones with Alkynylmagnesium Bromides

Sterically shielded nitroxides, which demonstrate high resistance to bioreduction, are the spin labels of choice for structural studies inside living cells using pulsed EPR and functional MRI and EPRI in vivo. To prepare new sterically shielded nitroxides, a reaction of cyclic nitrones, including va...

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Detalles Bibliográficos
Autores principales: Dobrynin, Sergey A., Gulman, Mark M., Morozov, Denis A., Zhurko, Irina F., Taratayko, Andrey I., Sotnikova, Yulia S., Glazachev, Yurii I., Gatilov, Yuri V., Kirilyuk, Igor A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9654931/
https://www.ncbi.nlm.nih.gov/pubmed/36364453
http://dx.doi.org/10.3390/molecules27217626