Three for the Price of One: Concomitant I⋯N, I⋯O, and I⋯π Halogen Bonds in the Same Crystal Structure

The ditopic molecule 3-(1,3,5-trimethyl-1H-4-pyrazolyl)pentane-2,4-dione (HacacMePz) combines two different Lewis basic sites. It forms a crystalline adduct with the popular halogen bond (XB) donor 2,3,5,6-tetrafluoro-1,4-diiodobenzene (TFDIB) with a HacacMePz:TFDIB ratio of 2:3. In a simplified pic...

Descripción completa

Detalles Bibliográficos
Autores principales: van Terwingen, Steven, Wang, Ruimin, Englert, Ulli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9657311/
https://www.ncbi.nlm.nih.gov/pubmed/36364376
http://dx.doi.org/10.3390/molecules27217550

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9657311/
https://www.ncbi.nlm.nih.gov/pubmed/36364376
http://dx.doi.org/10.3390/molecules27217550

Ejemplares similares