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Reaction of Corroles with Sarcosine and Paraformaldehyde: A New Facet of Corrole Chemistry

Details on the unexpected formation of two new (dimethylamino)methyl corrole isomers from the reaction of 5,10,15-tris(pentafluorophenyl)corrolatogallium(III) with sarcosine and paraformaldehyde are presented. Semi-empirical calculations on possible mechanism pathways seem to indicate that the new c...

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Detalles Bibliográficos
Autores principales: Barata, Joana F. B., Lacerda, Paula S. S., Neves, Maria Graça P. M. S., Cavaleiro, José A. S., Ramos, Catarina I. V., Tomé, Augusto C., Abreu, Paulo E., Pais, Alberto A. C. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9658120/
https://www.ncbi.nlm.nih.gov/pubmed/36362367
http://dx.doi.org/10.3390/ijms232113581