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ThC(2)@C(82)versus Th@C(84): unexpected formation of triangular thorium carbide cluster inside fullerenes

Synthesis of the first thorium-containing clusterfullerenes, ThC(2)@C(s)(6)–C(82) and ThC(2)@C(2)(5)–C(82), is reported. These two novel actinide fullerene compounds were characterized by mass spectrometry, single-crystal X-ray diffraction crystallography, UV–vis–NIR spectroscopy, and theoretical ca...

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Detalles Bibliográficos
Autores principales: Shen, Yi, Yu, Xiaojuan, Meng, Qingyu, Yao, Yang-Rong, Autschbach, Jochen, Chen, Ning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667913/
https://www.ncbi.nlm.nih.gov/pubmed/36425487
http://dx.doi.org/10.1039/d2sc04846a