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ThC(2)@C(82)versus Th@C(84): unexpected formation of triangular thorium carbide cluster inside fullerenes
Synthesis of the first thorium-containing clusterfullerenes, ThC(2)@C(s)(6)–C(82) and ThC(2)@C(2)(5)–C(82), is reported. These two novel actinide fullerene compounds were characterized by mass spectrometry, single-crystal X-ray diffraction crystallography, UV–vis–NIR spectroscopy, and theoretical ca...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667913/ https://www.ncbi.nlm.nih.gov/pubmed/36425487 http://dx.doi.org/10.1039/d2sc04846a |