Ligand-free nickel catalyzed perfluoroalkylation of arenes and heteroarenes

We describe a “ligand-free” Ni-catalyzed perfluoroalkylation of heteroarenes to produce a diverse array of trfiluoromethyl, pentafluoroethyl and heptafluoropropyl adducts. Catalysis proceeds at room temperature via a radical pathway. The catalytic protocol is distinguished by its simplicity, and its...

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Detalles Bibliográficos
Autores principales: Deolka, Shubham, Govindarajan, Ramadoss, Vasylevskyi, Serhii, Roy, Michael C., Khusnutdinova, Julia R., Khaskin, Eugene
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667918/
https://www.ncbi.nlm.nih.gov/pubmed/36425484
http://dx.doi.org/10.1039/d2sc03879j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667918/
https://www.ncbi.nlm.nih.gov/pubmed/36425484
http://dx.doi.org/10.1039/d2sc03879j

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