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Ligand-free nickel catalyzed perfluoroalkylation of arenes and heteroarenes

We describe a “ligand-free” Ni-catalyzed perfluoroalkylation of heteroarenes to produce a diverse array of trfiluoromethyl, pentafluoroethyl and heptafluoropropyl adducts. Catalysis proceeds at room temperature via a radical pathway. The catalytic protocol is distinguished by its simplicity, and its...

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Detalles Bibliográficos
Autores principales:	Deolka, Shubham, Govindarajan, Ramadoss, Vasylevskyi, Serhii, Roy, Michael C., Khusnutdinova, Julia R., Khaskin, Eugene
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667918/ https://www.ncbi.nlm.nih.gov/pubmed/36425484 http://dx.doi.org/10.1039/d2sc03879j

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