C(sp(3))–C(sp(3)) coupling of non-activated alkyl-iodides with electron-deficient alkenes via visible-light/silane-mediated alkyl-radical formation

Here, we present a remarkably mild and general initiation protocol for alkyl-radical generation from non-activated alkyl-iodides. An interaction between a silane and an alkyl iodide is excited by irradiation with visible light to trigger carbon–iodide bond homolysis and form the alkyl radical. We sh...

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Detalles Bibliográficos
Autores principales: Mistry, Sanesh, Kumar, Roopender, Lister, Andrew, Gaunt, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667957/
https://www.ncbi.nlm.nih.gov/pubmed/36425511
http://dx.doi.org/10.1039/d2sc03516b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9667957/
https://www.ncbi.nlm.nih.gov/pubmed/36425511
http://dx.doi.org/10.1039/d2sc03516b

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