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The Elusive Mononitrosylated [Fe(4)S(4)] Cluster in Three Redox States

Iron‐sulfur clusters are well‐established targets in biological nitric oxide (NO) chemistry, but the key intermediate in these processes—a mononitrosylated [Fe(4)S(4)] cluster—has not been fully characterized in a protein or a synthetic model thereof. Here, we report the synthesis of a three‐member...

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Detalles Bibliográficos
Autores principales: Kim, Youngsuk, Sridharan, Arun, Suess, Daniel L. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9669169/
https://www.ncbi.nlm.nih.gov/pubmed/36194444
http://dx.doi.org/10.1002/anie.202213032