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The Elusive Mononitrosylated [Fe(4)S(4)] Cluster in Three Redox States
Iron‐sulfur clusters are well‐established targets in biological nitric oxide (NO) chemistry, but the key intermediate in these processes—a mononitrosylated [Fe(4)S(4)] cluster—has not been fully characterized in a protein or a synthetic model thereof. Here, we report the synthesis of a three‐member...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9669169/ https://www.ncbi.nlm.nih.gov/pubmed/36194444 http://dx.doi.org/10.1002/anie.202213032 |