Glycal mediated synthesis of piperidine alkaloids: fagomine, 4-epi-fagomine, 2-deoxynojirimycin, and an advanced intermediate, iminoglycal

Glucal and galactal are transformed into 2-deoxyglycolactams, which are important building blocks in the synthesis of biologically active piperidine alkaloids, fagomine and 4-epi-fagomine. In one of the strategies, reduction of 2-deoxyglycolactam-N-Boc carbonyl by lithium triethylborohydride (Super-...

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Detalles Bibliográficos
Autores principales: Chand, Hemender R., Tiwari, Mritunjay K., Bhattacharya, Asish K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9670682/
https://www.ncbi.nlm.nih.gov/pubmed/36425185
http://dx.doi.org/10.1039/d2ra05224e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9670682/
https://www.ncbi.nlm.nih.gov/pubmed/36425185
http://dx.doi.org/10.1039/d2ra05224e

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