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Nickel-catalyzed switchable 1,3-dienylation and enantioselective allenylation of phosphine oxides

The development of general catalytic methods for the regio- and stereoselective construction of phosphoryl derivatives from identical substrates remains a formidable challenge in organic synthesis. Enabled by the newly developed BDPP-type ligands, we disclosed a nickel-catalyzed allenylation of phos...

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Detalles Bibliográficos
Autores principales: Zhang, Jiayin, Chang, Xihao, Xu, Xianghong, Wang, Hongyi, Peng, Lingzi, Guo, Chang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9671958/
https://www.ncbi.nlm.nih.gov/pubmed/36396661
http://dx.doi.org/10.1038/s41467-022-34764-x