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The stable “F–SO(2)(+)” donor provides a mild and efficient approach to nitriles and amides

In this update, we developed a mild, efficient and practical method using fluorosulfuryl imidazolium salt A as an environment friendly promoter for conversion of oximes to nitriles or amides via β-elimination or Beckmann rearrangement in almost quantitative yield in 10 minutes. The target products w...

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Detalles Bibliográficos
Autores principales: Cui, Yin, Zhao, Yiyong, Shen, Junjie, Zhang, Guofu, Ding, Chengrong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9672908/
https://www.ncbi.nlm.nih.gov/pubmed/36425170
http://dx.doi.org/10.1039/d2ra05890a